kinetics of radical polymerizations of waterborne alkyd/acrylic hybrid resin via batch mini-emulsion technique was studied using redox initiators (tbhp/fe2+/edta/asac  and  tbhp/fe2+/edta/sfs) at relatively low temperatures and thermal initiators (bpo, kps and aibn) at higher temperatures to seek the most suitable initiator system. at the end of all reactions the unreacted monomer content was r...

modification of natural polymers like protein by graft co-polymerization is an important method to incorporate the desired properties into the backbone. soy protein concentrate (spc) was grafted with ethylmethacrylate (ema) using ascorbic acid /potassium persulphate as redox initiator system under pressure. different reaction parameters such as reaction time, reaction pressure, solvent amount, ...

Allylation and benzylation of p-quinones was achieved through an unusual redox chain reaction. Mechanistic studies suggest that the existence of trace hydroquinone initiates a redox chain reaction that consists of a Lewis acid catalyzed Friedel-Crafts alkylation and a subsequent redox equilibrium that regenerates hydroquinone. The electrophiles could be various allylic and benzylic esters. The ...

The Ce/ Ce redox system was studied to initiate the grafting of idustrial cellulose pulp with vinyl acetate monomer. The parameters of the copolymerization reaction (reaction time, temperature, monomer and initiator contentration, freeness, chemical composition of the cellulose) were investigated and their effects are discussed.

Cloisite Na+was used as a solid surfactant (stabilizer) in Pickering emulsion polymerization of styrene-co-butyl acrylate in presence of oil soluble initiator, azobisisobutyronitrile (AIBN) and water soluble initiator, potassium persulfate (KPS). Fourier transform infrared (FTIR) spectrum approved the corporation of Cloisite Na+ layers within the polymer matrix. Effect of clay content was a...

Redox changes are one of the factors that influence cell-cycle progression and that control the processes of cellular proliferation, differentiation, senescence and apoptosis. Proteins regulated through redox-sensitive cysteines have been characterized but specific 'sulphydryl switches' in replication proteins remain to be identified. In bovine papillomavirus type-1, DNA replication begins when...

Styrene-acrylate copolymer was synthesized in presence of carbon black through heterogeneous polymerization. The percentage of monomer conversion was measured by gravimetric method, also PSA, SEM, DSC and GPC were used for studying the particle size and particle size distribution, morphology, thermal properties and molecular weight, respectively. As well as color properties were characterized b...